ID 1.13.11.18 DE Sulfur dioxygenase. AN Sulfur oxygenase. CA Sulfur + O(2) + H(2)O = sulfite + 2 H(+). CF Iron. CC -!- Glutathione (GSH) plays a catalytic role in elemental sulfur CC activation, but is not consumed during the enzymic reaction. CC -!- GSH and elemental sulfur react non-enzymically to yield CC S-sulfanylglutathione and it is only in this form that the sulfur can CC be oxidized to yield sulfite. CC -!- The sulfite can be further converted into sulfate, thiosulfate or CC S-sulfoglutathione (GSSO(3)(-)) non-enzymically. //