ID 1.2.1.25 DE 2-oxoisovalerate dehydrogenase (acylating). CA 3-methyl-2-oxobutanoate + CoA + NAD(+) = 2-methylpropanoyl-CoA + CO(2) + CA NADH. CC -!- Also acts on (S)-3-methyl-2-oxopentanoate and 4-methyl-2- CC oxopentanoate. //